i have created one sample grid for you..it does not do anything but just to show you how you can create the layout of your choice by using template column,below is mark up for it
<asp:GridView ID="sampleGrid" runat="server" AutoGenerateColumns="True"
CellPadding="4" ForeColor="#333333" GridLines="None">
<RowStyle BackColor="#EFF3FB" />
<Columns>
<asp:TemplateField HeaderText="HeaderColumn1">
<ItemTemplate>
<label></label>
</ItemTemplate>
</asp:TemplateField>
<asp:TemplateField HeaderText="HeaderColumn2">
<ItemTemplate>
<table border="1" width="100%">
<tr>
<td>
Col1
</td>
</tr>
<tr>
<td>
Col2
</td>
<td>
Col3
</td>
</tr>
</table>
</ItemTemplate>
</asp:TemplateField>
<asp:TemplateField HeaderText="HeaderColumn3">
<ItemTemplate>
<table border="1" width="100%">
<tr>
<td>
Col1
</td>
<td>
Col2
</td>
</tr>
</table>
</ItemTemplate>
</asp:TemplateField>
</Columns>
<FooterStyle BackColor="#507CD1" Font-Bold="True" ForeColor="White" />
<PagerStyle BackColor="#2461BF" ForeColor="White" HorizontalAlign="Center" />
<SelectedRowStyle BackColor="#D1DDF1" Font-Bold="True" ForeColor="#333333" />
<HeaderStyle BackColor="#507CD1" Font-Bold="True" ForeColor="White" />
<EditRowStyle BackColor="#2461BF" />
<AlternatingRowStyle BackColor="White" />
</asp:GridView>
now you will write your DataBinder tag inside any of your control where you would like to display the value from db right,but here i am showing how its devided in column and formated..see snapshot